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Adsorption and inhibition performance of the novel cationic Gemini surfactant as a safe corrosion inhibitor for carbon steel in hydrochloric acid |
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| Authors: | M Abdallah M A Hegazy M Alfakeer H Ahmed |
| Institution: | 1. Chemistry Department, Faculty of Science, Benha University, Benha, Egypt;2. Chemistry Department, Faculty of Applied Sciences, Umm Al-Qura University, Makkah, Saudi Arabiametwally555@yahoo.com;4. Egyptian Petroleum Research Institute (EPRI), Nasr City, Cairo, Egypt;5. Chemistry Department, Faculty of Science, Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia |
| Abstract: | The new synthesized cationic Gemini surfactant (CGS) was tested as a corrosion inhibitor for carbon steel (CS) in 1.0?M hydrochloric acid using weight loss, electrochemical spectroscopy and potentiodynamic polarization. The inhibition efficiency is increased by increasing the CGS concentration and is almost constant within the temperature range studied. The inhibition was explained by adsorption of the CGS molecule on the CS surface. A mixed-type inhibitor is suggested for the inhibitory effects of CGS as revealed by the potentiodynamic polarization technique. The changes in impedance parameters suggested that the adsorption of the inhibitor on the CGS surface led to the formation of protective films. The adsorption of the CGS on the surface of CS obeys Langmuir adsorption isotherm. Thermodynamic and kinetic parameters were calculated and discussed. |
| Keywords: | Steel EIS weight loss polarization acid inhibition interfaces |