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Review: recent advances in the chemistry of metal chelate monomers |
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| Authors: | Gulzhian I Dzhardimalieva |
| Institution: | Laboratory of Metallopolymers, The Institute of Problems of Chemical Physics RAS, Chernogolovka, Moscow Region, Russian Federation |
| Abstract: | This review summarizes recent advances in the chemistry of metal chelate monomers. Depending on the character of bonding of the metal to the chelating fragment, metal chelate monomers are divided into four main types: molecular metal chelates, intracomplex compounds, macrocyclic complexes, and polynuclear metal chelates. The synthetic methodologies for preparing metal chelate monomers are systematized. Special attention is paid to the effect of a metal on both the polymerization transformations of the metal chelate monomers and properties of the products formed. The bibliography includes papers published after 2010. |
| Keywords: | Metal chelate monomers molecular metal chelates intracomplex compounds macrocyclic complexes polynuclear metal chelates polymerization copolymerization electropolymerization polycondensation polymeric metal chelates |