Reactions of pentachloro-2-nitrobutadiene with some aliphatic and heterocyclic thiols and a crystallographic study |
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Authors: | Cemil Ibis Sibel Sahinler Ayla Şenol Yavuz Hatice Asar Funda Özkök Hakan Bahar |
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Affiliation: | 1. Department of Chemistry, Organic Chemistry, Istanbul University, Istanbul, Turkeyibiscml@istanbul.edu.tr;3. Department of Chemistry, Organic Chemistry, Istanbul University, Istanbul, Turkey |
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Abstract: | In this study, S-, S,S- and S,O-substituted novel nitrodiene compounds were synthesized. Cyclization products were formed when difunctional nucleophiles were used. The stereoisomerism of a heterocyclic nitrodiene is discussed with the help of XRD studies. The structures of all compounds were characterized by spectroscopic methods (FT-IR, 1H NMR, 13C NMR, 19F NMR, MS) and microanalysis. |
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Keywords: | 2-nitro-butadiene thiols cyclization reaction crystal structure |
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