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Characterization of Vegetables by Stable Isotopic and Elemental Signatures
Authors:Gabriela Cristea  Ioana Feher  D Alina Magdas  Cezara Voica  Romulus Puscas
Institution:1. Department of Mass Spectrometry, Chromatography and Applied Physics, National Institute for Research and Development of Isotopic and Molecular Technologies, Cluj-Napoca, Romaniagabriela.cristea@itim-cj.ro;3. Department of Mass Spectrometry, Chromatography and Applied Physics, National Institute for Research and Development of Isotopic and Molecular Technologies, Cluj-Napoca, Romania
Abstract:ABSTRACT

109 Romanian parsley, celery and parsnip root, cucumber, vegetable marrow, onion, and pepper samples were characterized by their stable isotope ratios and elemental concentrations in comparison to imported varieties. Organic and conventional agriculture practices were also compared as well as a differentiation between eggplant and peppers grown in greenhouses and those in the field. δ2H values were between ?70.8 and 5.6‰, while the δ18O values were between ?9.0 and 4.1‰. The δ15N values for white onions were from 2.8 to 11.1‰. For Romanian organic onions, the carbon isotopic values were lower (?29.2 to ?28.2‰) compared to conventional onions from other countries (?27.8‰ to ?23.8%). Linear discriminant analysis was used to characterize agricultural practices and the geographic origin of the vegetables.
Keywords:Conventional  inductively coupled plasma-mass spectrometry (ICP-MS)  isotope ratio mass spectrometry  linear discriminant analysis  organic  vegetable
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