Construction of new cross-linked supramolecular polymer with FRET phenomenon based on oligo(p-phenylenevinylene)-linked pillar[5]arene dimer |
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Authors: | Ali Wajahat Xiaohan Li Le Fang Guiling Ning |
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Institution: | State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian, PR. China. |
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Abstract: | Cross-linked supramolecular polymers generally show distinct mechanical properties with intriguing functions, which have become one of the hot research topics in recent years. However, the cross-linked supramolecular polymers functionalised with fluorescence resonance energy transfer (FRET) properties have been rarely reported yet. Herein, a new cross-linked supramolecular polymer equipped with efficient FRET property was constructed successfully. The oligo(p-phenylenevinylene)-linked pillar5]arene dimer (PA-OPV) functioned as a host and energy donor, while four pentanenitrile groups coupled porphyrin (CN-Por) acted as guest with energy acceptor. The supramolecular polymerisation and FRET properties were investigated by using NMR, viscosity, Fluorescence, UV–vis and SEM. |
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Keywords: | Cross-linked supramolecular polymer pillararene FRET |
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