Tetrazoleacetic acid templated 3d-4f heterometallic-organic frameworks constructed from different ligands: structures,luminescence, magnetism and photocatalytic properties |
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| Authors: | Lin-Xia Zhou Jian-Qing Xu Hong-Lin Zhu |
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| Affiliation: | 1. Joint Laboratory for Environmental Test and Photocatalytic Research of Ningbo University-Zhejiang Zhonghao Applied Engineering Technology Institute Co., Ltd., Ningbo University, Ningbo, P. R. China;2. Research Center of Applied Solid State Chemistry, Chemistry Institute for Synthesis and Green Application, Ningbo University, Ningbo, P. R. China |
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| Abstract: | A series of 3-D lanthanide-transition 3d-4f heterometallic complexes have been synthesized by hydrothermal route from mixtures of 2,2′-bipyridyl-5,5′-dicarboxylic acid (H2bpdc) and acetic acid (HAc) with tetrazoleacetic acid as template. The single-crystal X-ray analysis shows that nine CdLn(H2O)2Cl2(bpdc)Ac complexes (Ln = La for 1, Pr for 2, Nd for 3, Sm for 4, Eu for 5, Gd for 6, Dy for 7, Ho for 8, Er for 9) crystallized in the space group P-1 and featured three-nodal (3, 4, 6)-three connected topological frameworks. The photocatalytic behaviors imply that 1–9 have significant photocatalytic activities for degradation of RhB. |
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| Keywords: | Heterometallic coordination polymers lanthanide contraction photocatalytic degradation properties |
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