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蓝色圆珠笔油墨紫外光照射变化的研究
引用本文:王俭,孙素琴,罗国安,张振宇,王彦吉,冯计民.蓝色圆珠笔油墨紫外光照射变化的研究[J].分析化学,2000,28(9):1107-1109.
作者姓名:王俭  孙素琴  罗国安  张振宇  王彦吉  冯计民
作者单位:1. 清华大学化学系,北京,100084
2. 中国刑警学院刑事科学技术系,沈阳110035
3. 公安部物证鉴定中心,北京100038
摘    要:在紫外光照射下,通过对蓝色圆珠笔字迹色痕FT-IR显微光谱的研究。发现溶剂挥发迅速。其次是环氧树脂的聚合、交联;三苯甲烷染料的分解比较缓慢;而醇酸树脂相对稳定。该研究为字迹色痕的进一步分辨提供了新方法,同时为字迹色痕的“年龄”推断奠定了基础。选用相关峰的相对峰高比来描述这一变化,并进行曲线拟合,消除了因笔力不同而引起的油墨流出量不同造成的误差,这在实际工作中是很有意义的。

关 键 词:FT-IR显微光谱法  字迹测试  蓝色圆珠笔油墨

Research About the Variation of Blue Ballpoint Writting Inks Exposured to Ultraviolet Light by Time
Wang Jian,Sun Suqin,Luo Guoan,Zhang Zhenyu,Wang Yanji,Feng Jimin.Research About the Variation of Blue Ballpoint Writting Inks Exposured to Ultraviolet Light by Time[J].Chinese Journal of Analytical Chemistry,2000,28(9):1107-1109.
Authors:Wang Jian  Sun Suqin  Luo Guoan  Zhang Zhenyu  Wang Yanji  Feng Jimin
Abstract:The Fourier transform-infrared spectra of the blue ballpoint inks exposed to ultraviolet light were studied. This research discovered that the solvents volatilized rapidest, and then the rate of polymerization and cross-link process of the epoxy resin took second place, and the decomposition of triarylmethane dyes was slower, and alkyd resin was relatively steady. It was as a new means for further distingusihing writting inks. Meanwhile, the means could determine the age of inks. The relative ratio of peak height was applied to describe the process of the change and on the basis of the curve fitting the errors coming from different strokes could be aviod. The advantages above are very important in practical examinations.
Keywords:Ballpoint whiting inks  Fourier transform-infrared  microspectrosocopy  ballpoint ink ag(  
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