A bis(phosphinimino)methanide lanthanum amide as catalyst for the hydroamination/cyclisation, hydrosilylation and sequential hydroamination/hydrosilylation catalysis |
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| Authors: | Rastätter Marcus Zulys Agustino Roesky Peter W |
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| Institution: | Institut für Chemie und Biochemie, Freie Universit?t Berlin, Fabeckstrasse 34-36, 14195, Berlin, Germany. |
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| Abstract: | LaN(SiHMe2)2]2CH(PPh2NSiMe3)2]], which was obtained via an amine elimination starting from CH2(PPh2NSiMe3)2] and LaN(SiHMe2)2]3(THF)2], was used as catalyst for the hydroamination/cyclisation, the hydrosilylation and the sequential hydroamination/hydrosilylation reaction. |
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