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Radical Copolymerization of Vinylidene Chloride with 3(2-Methyl)-6-methylpyridazinone in Several Solvents
Authors:Jun-Ichi Asakura  Masakuni Yoshihara  Takaaki Shindo  Yoshio Matsubara  Toshihisa Maeshima
Affiliation:1. 1st Department of Biochemistry , Kinki University School of Medicine , Sayama-cho Minamikawachi-gun, Osaka, 589, Japan;2. Department of Applied Chemistry Faculty of Science and Engineering , Kinki University , Higashi-Osaka, Osaka, 577, Japan
Abstract:The radical copolymerization of vinylidene chloride (Vc, M1) with 3(2-methyl)-6-methylpyridazinone (I, M2) was carried out in benzene, ethanol, phenol, and acetic acid at 60 and 80°C. The monomer reactivity ratios were found to vary with the reaction conditions. The linear correlationships were obtained by plotting the values of log r1 against those of V C[dbnd]O and V C[dbnd]C of monomers determined in the solvents.
Keywords:Methyl methacrylate  Microemulsion polymerization  Winsor I-like system
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