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Ruthenium deposited on MCM-41 as efficient catalyst for hydrolytic dehydrogenation of ammonia borane and methylamine borane
Authors:Lan Wen  Zhong Zheng  Wei Luo  Ping Cai  Gong-Zhen Cheng
Institution:a College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China; b Suzhou Institute of Wuhan University, Suzhou 215123, China
Abstract:Ultrafine Ru nanoparticles are successfully deposited on MCM-41 by using a simple liquid impregnationreduction method, and further investigated for catalytic hydrolysis of ammonia borane and methylamine borane. Among all the catalysts tested, 1.12 wt% Ru/MCM-41 exhibits the highest catalytic activity, with turnover frequency value of 288 min-1.
Keywords:MCM-41  Ru nanoparticles  Hydrogen storage  Ammonia borane  Methylamine  
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