NMR Study of Vulcanized Rubber |
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Authors: | Shizuo Fujiwara Kunihiko Fujimoto |
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Affiliation: | 1. Department of Chemistry , Faculty of Science The University of Tokyo , Bunkyoku, Tokyo, Japan;2. Central Research Institute Brudgestone Tire Co. , Kodaua, Tokyo, Japan |
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Abstract: | It is shown that NMR-linewidth measurements are useful to obtain information about the cross-linkage density and the average distance between the cross-links in vulcanized rubber. Inhomogeneous structure of the rubber phase in carbon-filled rubber is evidenced and the thickness of the rubber layer on carbon is evaluated at 50 Å. |
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