Cyclotriphosphazatriene Derivatives. XXIX. Reaction of Cyclophosphazatriene Dichloride With Sodium Hydrosulfide |
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| Authors: | M Kajiwara H Saito K Yamada S Ito |
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| Institution: | 1. Department of Applied Chemistry Faculty of Engineering , Nagoya University , Nagoya, shi, Japan;2. Government Industrial Development Laboratory Hokkaido , Sappro, shi, Japan |
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| Abstract: | The chlorine substitution reaction of trimeric dichlorocyclophosphazene with sodium hydrosulfide has been examined. The reaction proceeded easily in dioxane and THF solutions. The reaction product, which had the chemical composition P3N3S6H6, was examined by 31P-NMR and IR spectroscopy. Further, it is suggested that the product was polymerized by heating with hydrogen sulfide, and the polymer (PNS) was formed. |
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