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Crystallization Behavior and Crystal Morphology of PTT/PBT Blends
Authors:Guijuan Li  Kunyan Wang  Xueli Xu  Baojie Yu  Shugang Li  Yanmo Chen
Institution:1. College of Chemical Engineering , Chang Chun University of Technology , Chang Chun , P. R. China;2. State Key Laboratory for Modification of Chemical Fiber and Polymer Materials , Donghua University , Shanghai , P. R. China lgj@mail.dhu.edu.cn;4. College of Chemical Engineering , Chang Chun University of Technology , Chang Chun , P. R. China;5. State Key Laboratory for Modification of Chemical Fiber and Polymer Materials , Donghua University , Shanghai , P. R. China
Abstract:The crystallization behavior and crystal morphology of the poly(trimethyl terephthalate) (PTT)/poly(butylene terephthalate) (PBT) blends were investigated by means of differential scanning calorimetry (DSC), wide angle X‐ray diffraction (WAXD) and polarized light microscopy (PLM) techniques. It was found that the two components crystallized simultaneously in the crystalline regions. The degree of crystallinity changed with PTT content. Crystalline properties were worse when the ratio of PBT and PTT contents was close to 50:50, but were better when PBT content was greatly different from PTT content.
Keywords:PTT  PBT  blends  crystallization  degree of crystallinity  isothermal crystallization
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