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One-step synthesis of MnO2 doped poly(aniline-co-o-aminophenol) and the capacitive behaviors of the conducting copolymer
Authors:Xiu-Ying Hu  Qing-Xin Liu  Di Ma  Zhong Liu  Yong Kong  Huai-Guo Xue
Institution:a School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, China; b Science and Technology Department, Changzhou College of Information Technology, Changzhou 213164, China; c Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou 213164, China; d School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
Abstract:MnO2 was doped into a conducting copolymer, poly(aniline-co-o-aminophenol) (PANOA), via a one-step process during the chemical oxidative polymerization. The doping of MnO2 could enhance the electrochemical activity and reversibility of the copolymer. When used as the electrode materials of a supercapacitor, the capacitive behaviors of the as-prepared PANOA-MnO2 were superior to those of pure PANOA, especially at high potential scan rate and high charge-discharge current density. The MnO2 doped copolymer also had an excellent cyclic performance.
Keywords:Conducting copolymer  MnO2  One-step synthesis  Supercapacitor  
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