Conjugated radical cation dimerization-driven generation of supramolecular architectures |
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Authors: | Lan Chen Yun-Chang Zhang Wei-Kun Wang Jia Tian Liang Zhang Hui Wang Dan-Wei Zhang Zhan-Ting Li |
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Affiliation: | Department of Chemistry, Fudan University, Shanghai 200433, China |
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Abstract: | This paper summarizes the recent advance in utilizing conjugated radical cation dimerization(CRCD) for constructing new unimolecular, such as foldamers, and supramolecular ordered structures, such as three-dimensional supramolecular polymers and two-dimensional supramolecular organic framework.Particularly, the stacking or dimerization of tetrathiafulvalene and 4,4'-dipyridium subunits has been highlighted, and the approaches for enhancing the stability of their radical cation dimers have been discussed. |
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