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Coordination Polymers. 9. Chelate Polymers Derived from Bisphenolic Complexes and Propylenediamine
Authors:Mihaela Spiratos  Anton Airinei  Gheorghe Ioan Rusu
Institution:“P. Poni” Institute of Macromolecular Chemistry Aleea Grigore , Ghica Voda, 41 A, R-6600, Iasi, Romania
Abstract:Chelate polymers derived from bis(2,4-dihydroxybenzaldehyde)propyl-enediimine M and bis(2,4-dihydroxyacetophenone)propylenediimine M (M = Fe2+, Co2+, Ni2+, Cu2+, Zn2+) with aromatic acid chlorides were prepared by interfacial polycondensation. Also, chelate polysiloxanes were obtained from the same monomers and α,ω-dichloropolydimethyl-siloxane. The spectral, thermal, magnetic, and electrical properties of the polychelates were studied.
Keywords:Siloxane  Cyclics  Cyclocarbosiloxane  Networks  Hydrosilylation
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