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Alternating and Random Copolymers of Vinyl Acetate and Maleic Anhydride
Authors:Raymond B. Seymour  David P. Garner  Laura J. Sanders
Affiliation:Department of Polymer Science , University of Southern Mississippi Hattiesburg , Mississippi, 39401
Abstract:Alternating copolymers of vinyl acetate (VAc) and maleic anhydride (MA) are produced preferentially when VAc and MA are copolymerized at moderate temperatures while random copolymers are produced at temperatures above 90°C. A charge-transfer complex (CTC) of VAc/MA exists at moderate temperatures but does not exist at temperatures above 90°C.
Keywords:PMMA  dendritic gelators  gel network  toughness  in-situ polymerization
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