Dissociation of Ethoxy Methyl Carbenium Hexachioroantimonate in Methylene Chloride Solution. II. The Nature and Extent of the Dissociation |
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| Authors: | C C MA H Garreau D R Squire V T Stannett M A Littlejohn |
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| Institution: | 1. Department of Chemical Engineering , North Carolina State University , Raleigh, North Carolina , 27607;2. Department of Electrical Engineering , North Carolina State University , Raleigh, North Carolina , 27607 |
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| Abstract: | Ethoxy methyl carbenium hexachioroantimonate has been synthesized as a model compound for the propagating species in the cationic polymerization of the vinyl ethers. Its degree of dissociation in methylene chloride has been studied as a function of concentration by using the method described in Part I. A simple one two dissociation was found. The degree of dissociation, however, was less than that found with a typical initiator such as triphenyl methyl hexachioroantimonate. |
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