Polyamides from Aromatic Bisamines-Chloral Derivatives and Terephthaloyl Chloride by Polycondensation in Solution |
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Authors: | Z. K. Brzozowski A. Grabowska-rostek Z. Przybysz |
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Affiliation: | Technical University of Warsaw , Warsaw, Poland |
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Abstract: | New aromatic polyamides from the bisamines 2,2-bis(p-amine-pheny1)-1, 1,1-trichloroethane (Bisamine I), 2,2-bis(p-amine-pheny1)-1,1-dichloroethylene (Bisamine II), and terephtaloil chloride were synthesized by means of several methods. It was found that low-temperature solvent polycondensation is optimum for obtaining polymers with the best properties, which are predominantly better in the case of polyamides based on Bisamine II. |
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