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13C-NMR Study of the Compounds Resulting from the Reaction of 5-Methylene-2-norbornene with Trifluoroacetic Acid
Authors:M Brigodiot  E Maréchal
Institution:Laboratoire de Synthése MacromolSeAculaire (LA 24 CNRS) , Université P. et M. Curie , Paris, France
Abstract:Isomerization of the adduct resulting from the protonation of 5-methylene-2-norbornene by trifluoroacetic acid was studied by UC-NMR spectroscopy. Relative rate constants were determined under various experimental conditions. The influence of temperature, solvent, and relative reactant concentrations was examined.
Keywords:PIB  Telechelic  Haloboration-Initiation  Dichloroborane  Azide  Sec-amine  NMR
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