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Cationic fac-tris(pyrazole) complexes as anion receptors
Authors:Nieto Sonia  Pérez Julio  Riera Víctor  Miguel Daniel  Alvarez Celedonio
Affiliation:Departamento de Química Orgánica e Inorgánica-IUQOEM, Facultad de Química-CSIC, Universidad de Oviedo, 33006, Oviedo, Spain.
Abstract:New receptors fac-[Re(CO)3(pz)3]BAr'4 (pz = 3,5-dimethylpyrazole or 3(5)-tert-butylpyrazole, Ar' = 3,5-(CF3)2C6H3), synthesized from [Re(OTf)(CO)5] and the pyrazoles, have been found to show a high affinity for chloride.
Keywords:
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