Mössbauer spectra and electric conductivities of bidentate base bridged iron(II) phthalocyanine |
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| Authors: | Ho-Hsiang Wei Huey-Lih Shyu |
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| Affiliation: | Department of Chemistry, Tamkang University, Tamsui, Taiwan;Chungtai Junior College of Medical Technology, Taichung, Taiwan |
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| Abstract: | Bidentate bridging base polymer complexes of iron(II) phthalocyanine FePcL, where L = pyrazine (pyz), 4,4′-bipyridine (bpy), trans-1,2-bis(4-pyridyl)ethylene (bpe), 1,2-bis(4-pyridyl)ethane (bpa) and 4,4′-trimethylene bipyridine (tmbpy), have been prepared, characterized and oxidized by iodine to give a range of iron(II) and iron(III) complexes (FePcL)n · Ix. The electrical conductivities and Mössbauer parameters both change with respect to the kinds of bidentate bridging bases. The conjugation of bridged ligand markedly effects the conductivity of the complexes. |
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| Keywords: | Author to whom correspondence should be addressed. |
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