Reinvestigation of a transmetallation synthesis of bis(cyclopentadienyl)samarium(II) and formation of a new soluble cyclopentadienylsamarium(II) compound |
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| Authors: | GB Deacon GN Pain TD Tuong |
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| Institution: | Chemistry Department, Monash University, Clayton, Victoria 3168, Australia |
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| Abstract: | The transmetallation reaction between (C5H5)2Hg and activated samarium metal in tetrahydrofuran (thf)/ether did not give (C5H5)2Sm(thf)2 but (C5H5)3Sm(thf), whilst reduction of the last compound with potassium in thf gave KSm(C5H5)3, a soluble organosamarium(II) complex. |
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| Keywords: | Author to whom correspondence should be addressed |
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