Highly stereoselective synthesis of a sex pheromone of the dry bean beetleCallosobruchus analis |
| |
| Authors: | O. A. Pinsker P. G. Tsiklauri N. Ya. Grigor'eva |
| |
| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
| |
| Abstract: | Total synthesis of 3-methylhept-2(Z)-enoic acid, a sex pheromone of the dry bean beetleCallosobruchus analis, has been performed using a previously developed highly stereoselective method of the construction of disubstituted (Z)-methylolefins based on the higher thermodynamic stability of (E)-isomers of α,β-disubstituted acroleins. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1385–1388, July, 1999. |
| |
| Keywords: | insect pheromones stereoselective synthesis higher thermodynamic stability of (E)-isomers of α ,β -disubstituted acroleins 3-methylhept-2(Z)-enoic acid 3-methylhept-2(Z)-enol |
| 本文献已被 SpringerLink 等数据库收录！ |
|
