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Correlation of physico-chemical,mechanical and electrical properties of ultraviolet-degraded poly(ethylene terephthalate)
Institution:1. Biopolymers and Nanostructures Laboratory, Faculty of Chemical Sciences, Universidad Autónoma de San Luis Potosí, Av. Manuel Nava No. 6, CP 78210 San Luis Potosí, S.L.P., Mexico;2. Materials Laboratory, Faculty of Chemical Sciences, Universidad Autónoma de San Luis Potosí, Av. Manuel Nava No. 6, CP 78210 San Luis Potosí, S.L.P., Mexico;3. Colloids and Interfaces Laboratory, Institute of Physics, Universidad Autónoma de San Luis Potosí, Av. Manuel Nava No. 6, CP 78210 San Luis Potosí, S.L.P., Mexico;4. Electrochemical Processes in Semiconductors Laboratory, Institute of Physics, Benemérita Universidad Autónoma de Puebla, Apdo, Postal J-48, C.P. 72570 Puebla, Pue, Mexico;1. Chemistry Department, Centre for Exact Sciences, Federal University of São Carlos (UFSCar), Rodovia Washington Luís, Km 235, 10 SP-310 São Carlos, Brazil;2. Department of Analytical Chemistry, Aragon Institute of Engineering Research I3A, CPS-University of Zaragoza, Torres Quevedo Building, María de Luna 3, 50018 Zaragoza, Spain;1. Cukurova University, Arts-Sciences Faculty, Physics Department, 01330, Adana, Turkey;2. Jazan University, Physics Department, P.O. Box 114, 45142, Jazan, Saudi Arabia;3. Manisa Celal Bayar University, Faculty of Arts and Sciences, Department of Physics, Muradiye, Manisa, Turkey;4. Ege University, Institute of Nuclear Sciences, 35100, Bornova, İzmir, Turkey;1. Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials Science and Engineering, Northeastern University, Shenyang, Liaoning 110819, China;2. College of Chemistry and Materials Engineering, Bohai University, Jinzhou, Liaoning 121007, China;3. Foshan Graduate School of Northeastern University, Foshan, Guangdong 528311, China;4. Research Center for Functional Materials, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044, Japan
Abstract:Poly(ethylene terephthalate) (PET) films have been exposed to ultraviolet radiation. Changes in physico-chemical, mechanical and electrical properties which occur in the films were examined. It was found that the specific viscosity, tensile strength, elongation at break, relative dielectric constant and dielectric strength decrease, while the dielectric loss factor, density, optical density of the ir spectrum band which refers to the trans form of the PET molecule, as well as the quantity of carboxylic end groups, increase.Least squares analysis and function straightening methods were used for the interpretation of the experimental data. Correlating relationships between measured parameters were established using the same methods.Special attention was paid to the changes in the electrical properties of poly(ethylene terephthalate), because no data are available so far. Mathematical correlations with chemical and mechanical properties were established.
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