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Reflectivity modification of polymethylmethacrylate by silicon ion implantation
Authors:Georgi B Hadjichristov  Victor Ivanov
Institution:a Georgi Nadjakov Institute of Solid State Physics, Bulgarian Academy of Sciences, 72 Tzarigradsko Chaussee Boulevard, 1784 Sofia, Bulgaria
b Sofia University, Faculty of Physics, 5 James Bourchier Boulevard, 1164 Sofia, Bulgaria
c Institut des Matériaux Jean Rouxel, UMR6502 CNRS, Nantes Atlantic Universities, 2 rue de la Houssiniere, 44 322 Nantes, France
Abstract:The effect of silicon ion implantation on the optical reflection of bulk polymethylmethacrylate (PMMA) was examined in the visible and near UV. A low-energy (30 and 50 keV) Si+ beam at fluences in the range from 1013 to 1017 cm−2 was used for ion implantation of PMMA. The results show that a significant enhancement of the reflectivity from Si+-implanted PMMA occurs at appropriate implantation energy and fluence. The structural modifications of PMMA by the silicon ion implantation were characterized by means of photoluminescence and Raman spectroscopy. Formation of hydrogenated amorphous carbon (HAC) layer beneath the surface of the samples was established and the corresponding HAC domain size was estimated.
Keywords:42  70  Jk  61  41  +e  61  82  Pv  78  30  Jw  78  40  Me  78  55  Kz  78  66  Qn  78  68  +m
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