Peisleyite an unusual mixed anion mineral--a vibrational spectroscopic study

The mineral peisleyite has been studied using a combination of electron microscopy and vibrational spectroscopy. Scanning electron microscope (SEM) photomicrographs reveal that the peisleyite morphology consists of an array of small needle-like crystals of around 1 microm in length with a thickness of less than 0.1 microm. Raman spectroscopy in the hydroxyl stretching region shows an intense band at 3506 cm(-1) assigned to the symmetric stretching mode of the OH units. Four bands are observed at 3564, 3404, 3250 and 3135 cm(-1) in the infrared spectrum. These wavenumbers enable an estimation of the hydrogen bond distances 3.052(5), 2.801(0), 2.705(6) and 2.683(6)A. Two intense Raman bands are observed at 1023 and 989 cm(-1) and are assigned to the SO(4) and PO(4) symmetric stretching modes. Other bands are observed at 1356, 1252, 1235, 1152, 1128, 1098 and 1067 cm(-1). The bands at 1067 cm(-1) is attributed to AlOH deformation vibrations. Bands in the low wavenumber region are assigned to the nu(4) and nu(2) out of plane bending modes of the SO(4) and PO(4) units. Raman spectroscopy is a useful tool in determining the vibrational spectroscopy of mixed hydrated multianion minerals such as peisleyite. Information on such a mineral would be difficult to obtain by other means.