Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: structural, EPR, paramagnetic 1H NMR, and electrochemical investigations |
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| Authors: | Tubbs Kyle J Szajna Ewa Bennett Brian Halfen Jason A Watkins Rex W Arif Atta M Berreau Lisa M |
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| Institution: | Department of Chemistry and Biochemistry, Utah State University, 0300 Old Main Hill, Logan, UT 84322-0300, USA. |
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| Abstract: | The first examples of mononuclear nitrogen/sulfur-ligated Co(II) alkoxide complexes, species of relevance to a reactive intermediate observed for Co(II)-substituted liver alcohol dehydrogenase, have been isolated and characterized by multiple methods including X-ray crystallography, EPR, paramagnetic (1)H NMR, and cyclic voltammetry. |
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