| Synthesis and Liquid Crystal Behaviors of 2,4-Dioxo-3-pentyl 4-decyloxy Cinnamate Rhodium （I） Complexes |
| |
| 引用本文： | 韩杰,张良辅,万文.Synthesis and Liquid Crystal Behaviors of 2,4-Dioxo-3-pentyl 4-decyloxy Cinnamate Rhodium （I） Complexes[J].中国化学,2003,21(11):1521-1524. |
| |
| 作者姓名： | 韩杰 张良辅 万文 |
| |
| 作者单位： | ChengduInstituteofOrganicChemistry,ChineseAcademyofSciences,Chengdu,Sichuan610041,China |
| |
| 摘 要： | The title complexes have been synthesized by the reaction of RhCI(CO)2]2 or RhCI(COD)]2 (COD = 1,5-cyclooctadiene)with the organic ligand 2,4-dioxo-3-pentyl 4-decyloxy cinnamate 2. The complex 3 based on dicarbonylrhodium(I) shows nematic phase, while the complex 4 containing rhodium(I) bound to a COD ligand is a nonmesogen. The relationship between molecular structures and liquid crystal behavior has also been discussed by means of computer-aided molecular modeling.
|
| 关 键 词： | 合成 液晶 2 4-二氧代-3-戊基-4-癸基氧代肉桂酸铑（I）配合物 [RhCI（CO）2]2 [RhCI（COD）]2 β-二酮 分子结构 |
Synthesis and Liquid Crystal Behaviors of 2,4-Dioxo-3-pentyl 4-decyloxy Cinnamate Rhodium(I) Complexes |
| |
| HAN,Jie a,b ZHANG,Liang-Fu,a WAN,Wen a a Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu,Sichuan ,China b.Synthesis and Liquid Crystal Behaviors of 2,4-Dioxo-3-pentyl 4-decyloxy Cinnamate Rhodium(I) Complexes[J].Chinese Journal of Chemistry,2003,21(11):1521-1524. |
| |
| Authors: | HAN Jie a b ZHANG Liang-Fu a WAN Wen a a Chengdu Institute of Organic Chemistry Chinese Academy of Sciences Chengdu Sichuan China b |
| |
| Institution: | HAN,Jie a,b ZHANG,Liang-Fu,a WAN,Wen a a Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu,Sichuan 610041,China b Department of Chemistry,Nankai University,Tianjin 300071,China |
| |
| Abstract: | The title complexes have been synthesized by the reaction of RhCl(CO)_2]_2 or _2 (COD=1,5-cyclooctadiene) with the organic ligand 2,4-dioxo-3-pentyl 4-decyloxy cinnamate 2. The complex 3 based on dicarbonylrhodium(I) shows nematic phase,while the complex 4 containing rhodium(I) bound to a COD ligand is a nonmesogen. The relationship between molecular structures and liquid crystal behavior has also been discussed by means of computer-aided molecular modeling. |
| |
| Keywords: | liquid crystal β‐diketonate rhodium (I) complex synthesis |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
