Spontaneous formation of a chiral supramolecular superhelix in the crystalline state using a single-stranded tetranuclear metallohelicate |
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| Authors: | Akine Shigehisa Matsumoto Takashi Nabeshima Tatsuya |
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| Institution: | Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan. |
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| Abstract: | An unprecedented one-handed coiled-coil structure was formed in the crystal of a Zn(3)La tetranuclear metallohelicate, in which the handedness of both the helical component and the helical array was well controlled by the chiral auxiliary of the flexible acyclic ligand. |
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