Synthesis of stereoisomers of 2,4-diaminoglutaric and 2,5-diaminoadipic acids |
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| Authors: | V P Krasnov E A Zhdanova M A Korolyova I M Bukrina M I Kodess V Kh Kravtsov V N Biyushkin |
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| Institution: | (1) Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 20 ul. S. Kovalevskoi, 620219 Ekaterinburg, Russian Federation;(2) Institute of Applied Physics, Academy of Sciences of Moldova, 5 ul. Akademiei, 277028 Kishinev, Moldova |
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| Abstract: | Stereoisomers of 2,4-diaminoglutaric and 2,5-diaminoadipic acids were synthesized from glutamic and 2-aminoadipic acids, respectively.
The stereochemistry of the products was established by1H NMR spectroscopy and X-ray analysis.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 333–337, February, 1997. |
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| Keywords: | 2 4-diaminoglutaric acid 2 5-diaminoadipic acid nucleophilic substitution stereoisomers racemization |
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