Use of TADDOLs and their derivatives in asymmetric synthesis |
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Authors: | Hé lè ne Pellissier [Author Vitae] |
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Affiliation: | Université Paul Cézanne, Aix-Marseille III, Institut Sciences Moléculaires de Marseille, UMR CNRS no 6263, Equipe Chirosciences, Service 541, Avenue Esc. Normandie-Niemen, 13397 Marseille Cedex 20, France |
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Abstract: | |
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Keywords: | Ac, acetyl Acac, acetylacetone Anth, anthracen-9-yl Ar, aryl BarF, tetrakis[3,5-bis(trifluoromethyl)phenyl]borate BINOL, 1,1&prime -bi-2-naphthol BIPOL, biphenol Bn, benzyl Boc, tert-butoxycarbonyl Box, bisoxazoline BSA, bis-(trimethylsilyl)acetamide BTPP, tert-butylimino-tri(pyrrolidino)phosphorane BTSP, bis(trimethylsilyl)peroxide Bu, butyl Bz, benzoyl C, cyclo Cbz, benzyloxycarbonyl Cod, cyclooctadiene Cp, cyclopentadienyl CPG, controlled-pore glass Cy, cyclohexyl Dba, (E,E)-dibenzylideneacetone DBU, 1,8-diazabicyclo[5.4.0]undec-7-ene DCE, 1,2-dichloroethane de, diastereomeric excess DME, 1,2-dimethoxyethane DMF, dimethylformamide ee, enantiomeric excess EPR, electron paramagnetic resonance Et, ethyl Fu, furyl Hex, hexyl L, ligand Me, methyl Menth, menthyl MOM, methoxymethyl Naph, naphthyl Nbd, norbornadiene NCS, N-chlorosuccinimide NFSI, N-fluorobenzenesulfonimide NIPAAm, N-isopropylacrylamide NOBIN, 2-amino-2-hydroxy-1,1&prime -binaphthalene Non, nonyl Nu, nucleophile Pent, pentyl Ph, phenyl PMB, p-methoxybenzoyl PMP, p-methoxyphenyl POM, polyoxometalate Pr, propyl PS, polystyrene SET, single-electron transfer TADDOL, α,α,α&prime ,α&prime -tetraphenyl-2,2-dimethyl-1,3-dioxolane-4,5-dimethanol TBS, tert-butyldimethylsilyl TFA, trifluoroacetic acid THF, tetrahydrofuran Thio, thiophene TMEDA, tetramethylethylenediamine TMS, trimethylsilyl Tol, tolyl Ts, 4-toluenesulfonyl (tosyl) |
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