Control between TICT and PET using chemical modification of N-phenyl-9-anthracenecarboxamide and its application to a crown ether type chemosensor |
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Authors: | Jeongsik Kim Hiroshi Nakamura |
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Institution: | a Division of Environmental Materials Science, Graduate School of Environmental Science, Hokkaido University, Sapporo, Hokkaido 060-0810, Japan b Section of Materials Science, Research Faculty of Environmental Earth Science, Hokkaido University, Sapporo, Hokkaido 060-0810, Japan |
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Abstract: | Both twisted intramolecular charge transfer (TICT) and photoinduced electron transfer (PET) relaxation processes of N-phenyl-9-anthrylcarboxamide derivatives can be characterized by modified substitution of the phenyl group. Introduction of a methoxy group to phenyl moiety quenched fluorescence of the anthracene using TICT or PET process, and was not retrieved even using highly viscous media. The introduction of a methylene unit induced fluorescence emissions using a solvent with both viscosity and polarity. This phenomenon demonstrates that the effects of both TICT and PET are involved in this system. Based on these data, we synthesized a novel crown ether derivative 7: its analytical usefulness as a fluorescent chemosensor for alkaline earth metal ions is reported herein. |
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Keywords: | Intramolecular charge transfer Donor-acceptor system Fluorescent chemosensor Modification |
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