A facile synthesis of alkyl substituted maleic anhydrides: radical approach |
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| Authors: | Artyom V. Messorosh Alexey V. Trukhin Evgenii V. Eliseenkov |
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| Affiliation: | Department of Chemistry, Saint-Petersburg State University, Saint-Petersburg 198504, Russia |
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| Abstract: | Synthetic background for the preparation of alkyl substituted maleic anhydrides and maleimides based on radical alkylation of 2,3-dichloromaleic anhydride (maleimide) by hydrocarbons was developed. The best conditions for the selective synthesis of 2-alkyl-3-chloro- and unsymmetrically substituted dialkylmaleic anhydrides were elaborated. |
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