Unconventional thermodynamically stable cis isomer and trans to cis thermal isomerization in reversibly photoresponsive [0.0](3,3')-azobenzenophane |
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Authors: | Norikane Yasuo Katoh Ryuzi Tamaoki Nobuyuki |
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Affiliation: | Nanotechnology Research Institute, National Institute of Advanced Industrial Science and Technology, Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. y-norikane@aist.go.jp |
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Abstract: | Sterically hindered [0.0](3,3')-azobenzenophane exhibits thermal trans-to-cis isomerization to the thermodynamically stable cis-cis isomer, and reversible photochemical isomerization with good fatigue resistance. |
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