Synthesis of a novel copper(II) complex and its crystal structure |
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| Authors: | Min Shi and Jian-Kang Jiang |
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| Institution: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China |
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| Abstract: | One novel chiral copper(II) complex was successfully synthesized from the reaction of chiral 1,3-thiazolidine-2-thione ligand with CuCl2 in dichloromethane in the presence of Et3N and DMAP at room temperature. Its unique crystal structure was unambiguously disclosed by X-ray analysis. The crystal is tetragonal, space group I4(1), space group a=15.0875(11), b=15.0875(11), c=19.362(3) Å,  =90, β=90, γ=90°, V=4407.4(8) Å3, Z=8, ρcalc=1.639 mg cm?3. |
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| Keywords: | Chiral copper(II) complex 1 3-Thiazolidine-2-thione Bidentate chiral ligand Crystal structure X-ray analysis |
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