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锂离子电池硅化物及其复合负极材料的研究
引用本文:闫俊美,黄惠贞,张静,杨勇. 锂离子电池硅化物及其复合负极材料的研究[J]. 电化学, 2005, 11(4): 416-419
作者姓名:闫俊美  黄惠贞  张静  杨勇
作者单位:厦门大学固体表面物理化学国家重点实验室厦门大学化学系,厦门大学固体表面物理化学国家重点实验室厦门大学化学系,厦门大学固体表面物理化学国家重点实验室厦门大学化学系,厦门大学固体表面物理化学国家重点实验室厦门大学化学系 福建厦门361005,厦门大学环境科学研究中心,福建厦门361005,福建厦门361005,福建厦门361005,福建厦门361005
摘    要:应用机械合金退火法合成Mg2S i及MnS i材料,并由机械球磨法制备系列Mg2S i/C复合材料.电化学性能研究表明:以硅化物与碳材料复合,即可明显提高原纯硅化物材料的可逆比容量及其循环稳定性,而球磨复合法则是实现硅化物材料复合的一种简单且有效方法.

关 键 词:锂离子电池  复合材料  Mg2Si  MnSi  
文章编号:1006-3471(2005)04-0416-04
收稿时间:2005-06-16
修稿时间:2005-06-30

Silicides and Composites Materials as Anodes for Lithium Ion Batteries
YAN Jun-mei,HUANG Hui-zhen,ZHANG Jing,YANG Yong. Silicides and Composites Materials as Anodes for Lithium Ion Batteries[J]. Electrochemistry, 2005, 11(4): 416-419
Authors:YAN Jun-mei  HUANG Hui-zhen  ZHANG Jing  YANG Yong
Affiliation:1. State Key Laboratary for Physical Chemistry of Solid Surface, Department of Chemistry, Xiamen University, Xiamen 361005, China; 2. Cencer for Environmental Science research of Xiamen University,Xiamen 361005, China
Abstract:The anode materials of Mg_(2)Si and MnSi were synthesized by mechanically activated annealing(MAA) techniques in this work and the in electrochemical performances were also studied.A series of composite materials of Mg_(2)Si and CNTs or CMS were prepared by ball-milling method respectively.The reversible capacities of the composites were higher than that of the pure Mg_(2)Si and pure carbon materials.The cyclic performances have been improved greatly by ball-milling of the Mg_(2)Si and carbon materials.Results show that ball-milling method is one kind of method to make alloy materials into practical use.
Keywords:Mg2Si  MnSi
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