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Thermally Stable and Resonance Enhanced Large Nonlinear Optical Properties In Poled Silica Films Doped with Thiazole Azo Dye
Authors:Hideki Nakayama  Okihiro Sugihara  Hisashi Fujimura  Ryoka Matsushima  Naomichi Okamoto
Institution:(1) The Graduate School of Electronic Science and Technology, Shizuoka University, 3-5-1 Johoku, Hamamatsu 432, Japan;(2) Faculty of Engineering, Shizuoka University, 3-5-1 Johoku, Hamamatsu 432, Japan
Abstract:Sol-gel processed poled silica films doped with novel nonlinear organic materials, thiazole azo dye (TA), are prepared in high concentration. Resonance enhanced second-order nonlinear optical coefficient of d33 = 154 pm/V is obtained from TA doped silica film (40 wt%) for the fundamental wavelength of 1064 nm. The value d33 is unvaried for at least 100 h under a high temperature condition (100°C) without any relaxation. Wavelength dependent second-order nonlinearity is also measured.
Keywords:thiazole azo dye  second harmonic generation (SHG)  poled silica film  resonance enhanced SHG  thermal stability
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