Lifetimes and the dynamics of hydrogen bonds in liquid water |
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Authors: | N. A. Chumaevskii M. N. Rodnikova S. A. Vinogradov |
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Affiliation: | (1) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia |
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Abstract: | Based on Raman spectra of light, heavy, and half-heavy water in the region of O-H and O-D stretching vibrations and on the independent-oscillator model, it is shown that a peculiarity of the liquid state of water is the nonequivalence of O-H groups of water molecules in hydrogen bonding. The structure of liquid water and the mechanism of its molecular mobility are considered in this context. |
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