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Binding of molecular magnesium hydrides to a zirconocene-enyne template |
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| Authors: | Georg Bender Thomas Wiegand Hellmut Eckert Roland Fröhlich Constantin G Daniliuc Christian Mück-Lichtenfeld Sylvester Ndambuki Tom Ziegler Gerald Kehr Gerhard Erker |
| Institution: | 1. Organisch‐Chemisches Institut der Universit?t Münster, Corrensstrasse 40, 48149 Münster (Germany);2. Institut für Physikalische Chemie and Graduate School of Chemistry, Corrensstrasse 28/30, 48149 Münster (Germany);3. Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, Alberta, T2N1N4 (Canada) |
| Abstract: | An enyne-zirconium complex stabilizes molecular magnesium hydride (MgH(2) ) and even a molecular hydride, nC(4) H(9) MgH. These systems feature magnesium olefin π?complexation. |
| Keywords: | hydrides magnesium olefins π complexes zirconium |
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