Stepwise assembly of homochiral coordination polymers based on the precursor of an enantiopure Yb(3)Mn(6) cluster |
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| Authors: | Yong Zheng La-Sheng Long Rong-Bin Huang Lan-Sun Zheng |
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| Institution: | State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China. lslong@xmu.edu.cn. |
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| Abstract: | Two homochiral coordination polymers, namely, Yb(III)(3)Mn(III)(6)(L)(6)(μ(2)-OMe)(6)(isonicotinate)(2)(HOMe)(2)]Yb(III)(3)Mn(III)(6)(L)(6)(μ(2)-OMe)(6)(isonicotinate)(2)(HOMe)(4)](NO(3))(2)·6MeOH·12H(2)O (5) (H(3)L = (S,E)-4-(2-hydroxybenzylideneamino)-2-hydroxybutanoic acid) and Yb(III)(3)Mn(III)(6)Na(L)(6)(μ(2)-OMe)(6)(OOCH)(3)]I·17H(2)O (6), have been constructed by utilizing a stable enantiopure Yb(III)(3)Mn(III)(6)(L)(6)(μ(2)-OMe)(6)](3+) (Yb(3)Mn(6)) cluster as a precursor. |
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