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I(2) promoted domino oxidative cyclization for one-pot synthesis of 2-acylbenzothiazoles via metal-free sp(3) C-H functionalization
Authors:Yan-Ping Zhu  Mi Lian  Feng-Cheng Jia  Mei-Cai Liu  Jing-Jing Yuan  Qing-He Gao  An-Xin Wu
Institution:Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, 430079, P. R. China. chwuax@mail.ccnu.edu.cn.
Abstract:An I(2) promoted domino protocol was developed to construct 2-acylbenzothiazoles from simple and readily available aromatic ketones/unsaturated methyl ketones and o-aminobenzenethiols. The reaction proceeded smoothly under metal-free and peroxide-free conditions.
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