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Enantioselective Hydrogenation of α,β-Unsaturated Cyclic Ketones by Double Asymmetric Induction Preparation of (R)-Muscone
摘    要:(R)-Muscone[(R)-6]isanodoriferouscomPoundisolatedfromthemalemuskdeer.BecauseofthenatUralsupplyisseverelylbotofanumberofSyntheticmethodshaveaPPearedintheliteratUre['].However,eachofthepublishedenahoselechveopthehcprocessessuffersfromoneormoreofthefollowingflollgandcomplicatedprocess,lowcheforcalandophcalvields,andscarcityofstartingmaterials[2].Inl98o,TrostetaldeveloPedashortprocesstoopthesize(dl)-musconeingoodcheforca1yteld,andthestartinmaterialiseasil3'a.ailablef3];Ouradriistoobtain(R)-mu…

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