Synthesis of E-alkenylsilanes with dithienosilole and their electrochemical and optical properties |
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Authors: | In-Sook Lee Young-Woo Kwak Dong-Ha Kim Yong Cho Joji Ohshita |
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Institution: | aDepartment of Chemistry, Kyungpook National University, Daegu 702-701, Republic of Korea;bR&D Center, Heesung Electronics Ltd., Hosan-Dong, Dalseo-Gu, Daegu 704-230, Republic of Korea;cDepartment of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan |
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Abstract: | A series of 2,6-bis(ethenylsilyl)-4,4-diphenyldithienosilole derivatives containing silylene-spacer were prepared by platinum-catalyzed hydrosilylation reaction. All the hydrosilylation proceeded regio- and stereoselectively to give solely β-(E)-adducts. The 2,6-bis(ethenylsilyl)-4,4-diphenyldithienosilole derivatives exhibit intense fluorescence emission and high quantum yields. The shoulder band of 9 in the emission spectrum was explained the intramolecular charge transfer from the electron-donating group (dimethylaminostyryl group) to electron-accepting group (dithienosilole moiety). These optical data are in good agreement with the results of theoretical calculations of model compounds at the level of B3LYP/6-31G(d,p). |
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Keywords: | Hydrosilylation Silylene-spacer 4 4-Diphenyldithienosilole Alkenylsilane Quantum yield |
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