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Effect of the medium on the reaction of |
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| Authors: | R. G. Makitra G. G. Midyana E. Ya. Pal’chikova |
| Affiliation: | (1) Institute of Fossil Fuels Geology and Geochemistry, National Academy of Sciences of Ukraine, Lviv, Ukraine;(2) Fossil Fuels Physical Chemistry Department, Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, ul. Nauchnaya 3a, Lviv, 79053, Ukraine |
| Abstract: | The selectivity in the reaction of tert-butyl hypochlorite with 2,3-dimethylbutane in various solvents may be described by a three-parameter correlation equation taking into account the ability of solvents to nonspecific solvation and their cohesion energy density. |
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