| Mssbauer谱学及其在熔渣铁离子行为研究中的应用张丽君 |
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| 引用本文： | 张丽君,施丹昭,李连福.Mssbauer谱学及其在熔渣铁离子行为研究中的应用张丽君[J].光谱学与光谱分析,2001,21(1). |
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| 作者姓名： | 张丽君 施丹昭 李连福 |
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| 作者单位： | 东北大学化学系, |
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| 摘 要： | 综述了M¨ossbauer谱学原理、基本参数和测定方法 ;分析了熔渣中铁离子行为 ,并从化学和谱学角度阐述了Fe2 +、Fe3 +tet 和Fe3+oct 离子的M¨ossbauer谱特征 ;讨论了铁离子行为与熔渣碱度、渣中全铁量及Na2 O、Al2 O3 含量的关系 ;提出该领域的研究前景
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| 关 键 词： | Mssbauer谱学 同质异能移位 四极分裂 络合离子 |
Mssbauer Spectroscopy and Its Application in the Study of Iron Cation Behavior in Molten Slags |
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| Lijun ZHANG,Danzhao SHI,Lianfu LI.Mssbauer Spectroscopy and Its Application in the Study of Iron Cation Behavior in Molten Slags[J].Spectroscopy and Spectral Analysis,2001,21(1). |
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| Authors: | Lijun ZHANG Danzhao SHI Lianfu LI |
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| Abstract: | The principle,parameters and determination methods of Mssbauer spectroscopy are summarized.The iron cation behavior in molten slags is analyzed and Mssbauer spectra characteristics of Fe2+,Fe3+tet and Fe3+oct ions are detailed chemically and spetroscopically.The relationship between iron cation behavior and basicity,total iron,Na2O and Al2O3 addition in slags is also discussed here. |
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