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负载金属镧的壳聚糖对氟离子的吸附动力学
引用本文:姚瑞华,孟范平,张龙军,马冬冬. 负载金属镧的壳聚糖对氟离子的吸附动力学[J]. 离子交换与吸附, 2009, 25(4)
作者姓名:姚瑞华  孟范平  张龙军  马冬冬
作者单位:海洋环境与生态教育部重点实验室,中国海洋大学,青岛,266100;海洋环境与生态教育部重点实验室,中国海洋大学,青岛,266100;海洋环境与生态教育部重点实验室,中国海洋大学,青岛,266100;海洋环境与生态教育部重点实验室,中国海洋大学,青岛,266100
基金项目:山东省优秀中青年科学家科研奖励基金 
摘    要:利用负载金属镧的壳聚糖对含氟水进行吸附处理.该除氟剂的最佳吸附条件:pH值为7,温度为323K,吸附时间为60min.吸附剂对F的吸附过程符合Langmuir等温线方程,对F的饱和吸附容量为476.190mg/g.吸附动力学符合拟二级速率方程,颗粒内扩散过程和液膜形成的边界层是吸附过程的主要限速步骤.

关 键 词:氟离子  壳聚糖  吸附动力学

ADSORPTION KINETICS OF FLUORIDE ION USING LANTHANUM-MODIFIED CHITOSAN
YAO Ruihua,MENG Fanping,ZHANG Longjun,MA Dongdong. ADSORPTION KINETICS OF FLUORIDE ION USING LANTHANUM-MODIFIED CHITOSAN[J]. Ion Exchange and Adsorption, 2009, 25(4)
Authors:YAO Ruihua  MENG Fanping  ZHANG Longjun  MA Dongdong
Affiliation:YAO Ruihua MENG Fanping ZHANG Longjun MA Dongdong Key Lab of Marine Environment Science , Ecology,Ministry of Education Ocean University of China,Qingdao 266100,China
Abstract:The water containing high fluoride ions was treated by the applicability of lanthanum-modified chitosan. The treatment conditions were optimized:pH value was 7,temperature was at 323K,and contact time was 60min. The equilibrium adsorption data were fitted reasonably well for Langmuir isotherm model,the maximum adsorption capacity for F-was 476.190mg/g. Adsorption kinetics study revealed that the adsorption process followed pseudo-second-order model,the adsorption process was complex,both the boundary of liq...
Keywords:Fluoride ion  Chitosan  Adsorption kinetics.  
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