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玻璃中的ZnS:Mn2+超微粒发光的量子尺寸效应
引用本文:陈一民,向卫东.玻璃中的ZnS:Mn2+超微粒发光的量子尺寸效应[J].发光学报,1995,16(4):262-264.
作者姓名:陈一民  向卫东
作者单位:1. 中国科学院激发态物理开放研究实验室, 长春 130021;2. 浙江大学材料科学系, 杭州 210027
基金项目:国家自然科学基金,中国科学院出发态物理开放研究实验室资助
摘    要:自从Bhargava等1]报道了化学反应合成的ZnS:Mn2+纳米微粒的光学性质,掺杂半导体纳米微粒发光性质的研究受到了极大的重视。掺杂纳米微粒有可能成为新的一类发光材料.本文报导用熔融法制备的ZnS:Mn2+玻璃在光学性质上的量子尺寸效应。

关 键 词:硫化锌    掺杂  纳米粒  量子尺寸效应
收稿时间:1995-07-13

QUANTUM SIZE EFFECT ON THE LUMINESCENCE OF ZnS:Mn2+ ULTRA FINE PARTICLES EMBEDED IN GLASSES
Chen Yimin,Xiang Weidong,Sun Lingdong,Jin ChunmingYang Hua,Wang Zhongchai,Huang Shihua,Yu Jiaqi.QUANTUM SIZE EFFECT ON THE LUMINESCENCE OF ZnS:Mn2+ ULTRA FINE PARTICLES EMBEDED IN GLASSES[J].Chinese Journal of Luminescence,1995,16(4):262-264.
Authors:Chen Yimin  Xiang Weidong  Sun Lingdong  Jin ChunmingYang Hua  Wang Zhongchai  Huang Shihua  Yu Jiaqi
Institution:1. Laboratory of Excited State Processes, Chinese Academy of Sciences, Changchun 130021;2. Department of Material Scitnct and Engintering, Zhejiang University. Hangzhou 210027
Abstract:Abstract The glasses doped with ZnS:Mn2+ nanocrystals were successfully fabricated to study the size effects on the luminescent properties of ZnS:Mn2+.Photoluminescence measurements show the characteristic Mn2+ emission from within the ZnS host crystaland photoluminescent excitation measurements show a large blue shift of the excitation peak which is indicative of the increased band gap. An increased intensity of the SA emission was observed with the decrease in the size of the ZnS:Mn2+ crystallites.
Keywords:
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