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A potential fluorescent Hg(II) chemosensor
Authors:Ke Feng  Kofi Bota
Affiliation:a Department of Chemistry, Laboratory for Electro-Optical Materials, and NASA Center for High Performance Polymers and Materials, Clark Atlanta University, Atlanta, GA 30314, USA
b US Army Edgewood Chemical and Biological Center, Aberdeen Proving Ground, MD 21010, USA
Abstract:An imidazole-based ligand has been evaluated for a potential fluorescent Hg(II) sensing probe. In water-acetonitrile solvent system, the ligand exhibits a unique selectivity towards Hg(II), which not only modulates fluorescence intensity but also shifts the emission band. The fluorescence reduction and the emission shift correlate with Hg(II) concentrations.
Keywords:Imidazole   Thiazole   Mercury complex   Fluorescence   Copper complex   Molecular probe
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