On the reduction of S-alkyl-thionocarbonates (xanthates) with phosphorus compounds |
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Authors: | Boivin Jean Jrad Rafik Juge Stéphanie Nguyen Van Tai |
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Affiliation: | Institut de Chimie des Substances Naturelles, C.N.R.S., Gif-sur-Yvette 91198, France. jean.boivin@icsn.cnrds-gif.fr |
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Abstract: | [reaction: see text] Reductive cleavage of the carbon-sulfur bond present in S-alkyl-thionocarbonates (xanthates) was achieved by high-yielding, tin-free radical reactions based on phosphorus reagents. The combination hypophosphorous acid/triethylamine/AIBN led to fast, efficient, and smooth formation of the alkane. Reduction with diethyl phosphite was sufficiently slow to permit sequential intermolecular addition of a 2-oxoalkyl xanthate onto an olefin followed by cleavage of the newly formed carbon-sulfur bond. |
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